Olympiacos 4–2 PSV Eindhoven
Round of 32 · 1st Leg · Thu 18 Feb 2021StadiumGeorgios Karaiskakis StadiumPiraeus, Greece
Match events
Minute by minute- 9'1–0 Goal: Andreas BouchalakisAssist: Mathieu Valbuena Olympiacos
- 14'1–1 Goal: Eran ZahaviAssist: Ibrahim Sangaré PSV Eindhoven
- 31' Yellow card: Ibrahim Sangaré PSV Eindhoven
- 37'2–1 Goal: Yann M'vila Olympiacos
- 38' Substitution: Timo BaumgartlOff: Olivier Boscagli PSV Eindhoven
- 39'2–2 Goal: Eran ZahaviAssist: Philipp Max PSV Eindhoven
- 45+2'3–2 Goal: Youssef El Arabi Olympiacos
- Half-time 3–2
- 57' Yellow card: Oleg Reabciuk Olympiacos
- 62' Yellow card: Ousseynou Ba Olympiacos
- 62' Yellow card: Bruma Olympiacos
- 62' Yellow card: Pablo Rosario PSV Eindhoven
- 68' Substitution: Georgios MasourasOff: Mathieu Valbuena Olympiacos
- 70' Substitution: Mauro JúniorOff: Mario Götze PSV Eindhoven
- 70' Substitution: Yorbe VertessenOff: Ibrahim Sangaré PSV Eindhoven
- 75' Substitution: Kostas FortounisOff: Youssef El Arabi Olympiacos
- 80' Substitution: Thanasis AndroutsosOff: Kenny Lala Olympiacos
- 80' Substitution: KokaOff: Bruma Olympiacos
- 80' Substitution: Marios VrousaiOff: Yann M'vila Olympiacos
- 83'4–2 Goal: Georgios Masouras Olympiacos
- 85' Substitution: Érick GutiérrezOff: Eran Zahavi PSV Eindhoven
- 85' Substitution: Marco van GinkelOff: Ryan Thomas PSV Eindhoven
Line-ups
Confirmed
Olympiacos4-2-3-14-2-4PSV Eindhoven
- 1 Sá
- 45 Reabciuk
- 24 Ba
- 15 Papastathopoulos
- 7280' Lala
- 5 Bouchalakis
- 680' M'vila
- 2780' Bruma
- 4 Camara
- 28A68' Valbuena
- 1175' El Arabi
- 38 Mvogo
- 31A Max
- 2838' Boscagli
- 33 Teze
- 22 Dumfries
- 6A70' Sangaré
- 18 Rosario
- 3085' Thomas
- 9 Malen
- 2770' Götze
- 785' Zahavi
Olympiacos bench
- 17Marios Vrousai80'
- 19Georgios Masouras68'
- 9Koka80'
- 14Thanasis Androutsos80'
- 7Kostas Fortounis75'
PSV Eindhoven bench
- 17Mauro Júnior70'
- 5Timo Baumgartl38'
- 53Yorbe Vertessen70'
- 15Érick Gutiérrez85'
- 14Marco van Ginkel85'