Match events
Minute by minute- 27' Yellow card: Yarek Gasiorowski PSV Eindhoven
- 30' Yellow card: Joey Veerman PSV Eindhoven
- 31'0–1 Goal: Scott McTominayAssist: Leonardo Spinazzola Napoli
- 35'1–1 Own goal: Alessandro Buongiorno own goal PSV Eindhoven
- 38'2–1 Goal: Ismael SaibariAssist: Guus Til PSV Eindhoven
- 42' Yellow card: Leonardo Spinazzola Napoli
- 45' Substitution: Armando ObispoOff: Yarek Gasiorowski PSV Eindhoven
- Half-time 2–1
- 54'3–1 Goal: Dennis ManAssist: Mauro Júnior PSV Eindhoven
- 57' Substitution: Juan JesusOff: Sam Beukema Napoli
- 57' Substitution: Miguel GutiérrezOff: Leonardo Spinazzola Napoli
- 58' Substitution: Noa LangOff: Billy Gilmour Napoli
- 70' Yellow card: Ismael Saibari PSV Eindhoven
- 73' Substitution: David NeresOff: Matteo Politano Napoli
- 76' Red card: Lorenzo Lucca Napoli
- 80'4–1 Goal: Dennis ManAssist: Joey Veerman PSV Eindhoven
- 84' Substitution: Couhaib DriouechOff: Ivan Perisic PSV Eindhoven
- 84' Substitution: Sergiño DestOff: Anass Salah-Eddine PSV Eindhoven
- 84' Substitution: Ricardo PepiOff: Guus Til PSV Eindhoven
- 84' Substitution: Eljif ElmasOff: Kevin De Bruyne Napoli
- 85'4–2 Goal: Scott McTominayAssist: David Neres Napoli
- 86'5–2 Goal: Ricardo PepiAssist: Couhaib Driouech PSV Eindhoven
- 88' Substitution: Paul WannerOff: Ismael Saibari PSV Eindhoven
- 89'6–2 Goal: Couhaib DriouechAssist: Ricardo Pepi PSV Eindhoven
- 90' Yellow card: Couhaib Driouech PSV Eindhoven
Line-ups
Confirmed
PSV Eindhoven4-2-3-14-5-1Napoli
- 32 Kovár
- 284' Salah-Eddine
- 345' Gasiorowski
- 22 Schouten
- 6 Flamingo
- 23A Veerman
- 17A Júnior
- 584' Perisic
- 3488' Saibari
- 27 Man
- 20A84' Til
- 32 Milinkovic-Savic
- 37A57' Spinazzola
- 4 Buongiorno
- 3157' Beukema
- 22 Di Lorenzo
- 8 McTominay
- 658' Gilmour
- 99 Anguissa
- 2173' Politano
- 1184' De Bruyne
- 27 Lucca
PSV Eindhoven bench
- 9Ricardo Pepi84'A
- 4Armando Obispo45'
- 10Paul Wanner88'
- 11Couhaib Driouech84'A
- 8Sergiño Dest84'
Napoli bench
- 3Miguel Gutiérrez57'
- 70Noa Lang58'
- 5Juan Jesus57'
- 7David Neres73'A
- 20Eljif Elmas84'